Research Scientist at CNR-ISTM
Expertise: inorganic/organic synthesis, spectroscopy, photochemistry
Alessio Orbelli Biroli was born on March 14, 1976. He obtained the degree in Chemistry at the University of Pavia on April 2, 2001 discussing a thesis entitled “Self organized fluorescent systems for neutral species recognition in solution”.
In February 2005 he obtained the Ph. Doctoral degree in Chemical Science at the University of Pavia, Ph. D. thesis title “Metal driven self-aggregation processes”.
May 2001-September 2001: Research cooperation at the University of Pavia.
November 2004-August 2005: Postdoctoral fellowship at the University of Pavia.
September 2005-August 2008: Research collaboration as “young researcher” on the project “Nano-organized or π-delocalised macro chromophores for nonlinear optics” (FIRB 2003) at the University of Milan.
September 2008-August 2009: Postdoctoral fellowship at the University of Milan to perform research on the project entitled “Symmetrically and asymmetrically substituted porphyrins for applications in solar cells and optical limiting” (PRISMA 2007).
September 2009-15th December 2009: Postdoctoral fellowship at the University of Milan to perform research on the project entitled “Design and use of new organometallic or coordination materials for third generation organic solar cells: Porphyrins and metalloporphyrins for application in solar cells” (CARIPLO 2008).
Since 16th December 2009 he has a permanent position as Research Scientist at the Institute of Molecular Science and Technology of the National Research Council (CNR-ISTM) of Milan.
He has been involved in several National projects funded by the Italian Ministry of University and Scientific Research (MIUR, FIRB 2003, PRISMA 2007), by CARIPLO Foundation (CARIPLO 2008) or by the European Community (FP7-NMP-2009 project 246124 ‘‘SANS’’); he is currently involved in a project funded by MIUR (PRIN 2010-2011 project 20104XET32 “DSSCX”).
He is co-author of 15 publications in international journals with high impact factor and several communications to national and international conferences.
His research activities can be divided into four main topics:
–Supramolecular coordination chemistry: study of assembling and disassembling processes of ligands, containing a fluorescent fragment, promoted by metal ions in solution.
–Nonlinear optics: nano-organization of NLO active organic chromophores on inorganic scaffold such as cyclotetrasiloxanes; theoretical and experimental study of dependence on the metal of the second order NLO responses of push-pull porphyrinic complexes substituted in meso position.
–Photoluminescent materials: synthesis and study of models of the silica surface with photoluminescent chromophores, in particular terthiophene; design, synthesis and characterization of Er3+ complexes with fluorinated ligands for applications in telecommunications.
–Photovoltaics: synthesis of push-pull porphyrinic photosensitizers, substituted in meso or in β-pyrrolic position, for DSSCs.
1. G. Di Carlo, A. Orbelli Biroli, M. Pizzotti, F. Tessore, V. Trifiletti, R. Ruffo, A. Abbotto, A. Amat, F. De Angelis, P. R. Mussini, Tetraaryl ZnII porphyrinates substituted at β-pyrrolic position as sensitizers in dye-sensitized solar cells: a comparison wih meso-disubstituted push-pull ZNII porphyrinates, Chem. Eur. J. 19 (2013) 10723.
2. P. R. Mussini, A. Orbelli Biroli, F. Tessore, M. Pizzotti, C. Biaggi, G. Di Carlo, M. G. Lobello, F. De Angelis, Modulating the electronic properties of asymmetric push-pull and symmetric Zn(II)-diarylporphyrinates with para substituted phenylethynyl moieties in 5,15 meso positions: a combined electrochemical and spectroscopic investigation, Electrochimica Acta 85 (2012) 509.
3. A. Orbelli Biroli, F. Tessore, M. Pizzotti, C. Biaggi, R. Ugo, S. Caramori, A. Aliprandi, C. Bignozzi, F. De Angelis, G. Giorgi, E. Licandro, E. Longhi, A multitechnique physicochemical investigation of various factors controlling the photoaction spectra and of some aspects of the electron transfer for a series of push-pull Zn(II) porphyrins acting as dyes in DSSCs, J. Phys. Chem. C 155 (2011) 23170.
4. M. Ronchi, A. Orbelli Biroli, D. Marinotto, M. Pizzotti, M. C. Ubaldi, S. M. Pietralunga, The role of the chromophore size and shape on the SHG stability of PMMA films with embebbed NLO active macrocyclic chromophores based on a cyclotetrasiloxane scaffold, J. Phys. Chem. C 115 (2011) 4240.
5. W. Mróz, J. P. Bombenger, C. Botta, A. Orbelli Biroli, M. Pizzotti, F. De Angelis, R. Tubino, F. Meinardi, Oligothiophenes nano-organised on a cyclotetrasiloxane scaffold as a model of a silica bound monolayer: evidence for intramolecular excimer formation, Chem. Eur. J. 15 (2009) 12791.
6. M. Pizzotti, F. Tessore, R. Ugo, A. Orbelli Biroli, F. De Angelis, S. Fantacci, A. Sgamellotti, D. Zuccaccia, A. Macchioni, An EFISH, theoretical, and PGSE NMR investigation on the relevant role of aggregation on the second order NLO response in CHCl3 of the push-pull [5-[[4’-(dimethylamino)phenyl]ethynyl]-15-[(4”-nitrophenyl)ethynyl]-10,20-diphenylporphyrinate] M(II) (M= Zn, Ni), J. Phys. Chem. C113 (2009) 11131.
7. M. Ronchi, M. Pizzotti, A. Orbelli Biroli, S. Righetto, R. Ugo, P. Mussini, M. Cavazzini, E. Lucenti, M. Salsa, P. Fantucci, Second-order nonlinear optical (NLO) properties of a multichromophoric system based on an ensemble of four organic NLO chromophores nanoorganized on a cyclotetrasiloxane architecture, J. Phys. Chem. C 113 (2009) 2745.
8. A. Monguzzi, R. Tubino, F. Meinardi, A. Orbelli Biroli, M. Pizzotti, F. Demartin, G. Bongiovanni, F. Cordella, M. A. Loi, Novel Er3+ perfluorinated complexes for broadband sensitized near infrared emission, Chem. Mater. 21 (2009) 128.